Analysis of heavy metal migration in vegetable agricultural waste

Authors

  • Petro G. Kyrienko National Aerospace University “Kharkiv Aviation Institute”, Kharkiv, Ukraine
  • Tetyana O. Klocko National Aerospace University “Kharkiv Aviation Institute”, Kharkiv, Ukraine
  • Irina Y. Khomenko National Aerospace University “Kharkiv Aviation Institute”, Kharkiv, Ukraine
  • Ganna M. Durnevich National Aerospace University “Kharkiv Aviation Institute”, Kharkiv, Ukraine

DOI:

https://doi.org/10.32347/2411-4049.2020.4.32-40

Keywords:

heavy metals, migration, vegetable waste, fuel briquettes, fuel pellets

Abstract

One of the most important tasks facing Ukraine is to maximize the use of its own renewable energy resources, including the use of agricultural waste (stems, straw, sunflower husks, bonfires, etc.) to obtain energy sources such as fuel briquettes and pellets. The urgency of complete utilization of agricultural waste depends on the content of heavy metals in the ash formed during the combustion of fuel briquettes made from agricultural waste. The entry of heavy metals from the soil into plants today is a serious environmental problem, as a result of which human and animal food, as well as agricultural waste are contaminated with heavy metals. After making briquettes or pellets, they can be used as fuel in various installations. When briquettes or pellets is burning made from agricultural waste, ash is formed, which can be used as an additive to organic fertilizers, while heavy metals at high temperatures can form oxides and then salts, which are less susceptible to migration into plants. The analysis of migration of heavy metals from soil to plants is carried out. The possibility of using vegetable waste to obtain fuel briquettes and pellets is considered. The comparison of the content of heavy metals in the plant with the maximum permissible concentration was checked. The content of harmful substances in the ash was determined after their use. The scheme of technological sequence of production of briquettes and pellets from vegetable waste is presented. The possibility of using pellet ash and briquettes as additives to organic fertilizers is analyzed. In general, the processing of vegetable waste into fuel briquettes and pellets is a very effective environmental solution that allows the maximum use of agricultural waste as a renewable energy resource, as well as to bind heavy metals and prevent their further migration.

Author Biographies

Petro G. Kyrienko, National Aerospace University “Kharkiv Aviation Institute”, Kharkiv

PhD, docent of the Department of chemistry, ecology and expert technologies

Tetyana O. Klocko, National Aerospace University “Kharkiv Aviation Institute”, Kharkiv

Senior lecturer of the Department of chemistry, ecology and expert technologies

Irina Y. Khomenko, National Aerospace University “Kharkiv Aviation Institute”, Kharkiv

Senior engineer of the Department of chemistry, ecology and expert technologies

Ganna M. Durnevich, National Aerospace University “Kharkiv Aviation Institute”, Kharkiv

Student of the Department of chemistry, ecology and expert technologies

References

Kirienko, P.G., Kalashnikova, V.I., & Varlamov, E.N. (2014). Production of fuel briquettes from organic waste. Еkologija i promyshlennost', 3, 87-90. (in Russian)

Kyrijenko, P.G., Kobrin, V.M., Nechyporuk, M.V., & Mirsultanova, L.R. (2012). The method of obtaining fuel briquettes. Pat. 98672 Ukrai'na, MPK (2006.01) S10L 5/44. Bjul. №11, vid 11.06.2012 r. (in Ukrainian).

Kyrijenko, A.P., Kyrijenko, P.G., Kalashnikova, V.I., & Ugrjumov, M.L. (2015). Device for making briquettes. Pat. 109598 Ukrai'na, MPK (2006.01) B30B 11/10, B27N 3/20. Bjul. №17, vid 10.09.2015 r. (in Ukrainian).

Kroi'k, G.A. (2011). Toxicological aspects of accumulation and distribution of heavy metals in soils of industrial agglomerations. Bioriznomanittja ta rol' tvaryn v ekosystemah: Materialy VI Mizhnarodnoi' naukovoi' konferencii (pp. 15-18). Dnipropetrovs'k: Vyd-vo DNU. (in Ukrainian).

Methodological guidelines for the determination of heavy metals in agricultural soils, crop production. (1992). Moskva. (in Russian)

Heletukha, H., & Zheliezna, T. (Bioenergetychna asociacija Ukrai'ny). (2015). Bioenergy instead of gas. Ekonomichna pravda. Retrieved from: http://www.epravda.com.ua/ publications/2015/01/9/520368/. (in Ukrainian).

Published

2020-12-22

How to Cite

Kyrienko, P. G., Klocko, T. O., Khomenko, I. Y., & Durnevich, G. M. (2020). Analysis of heavy metal migration in vegetable agricultural waste. Environmental Safety and Natural Resources, 36(4), 32–40. https://doi.org/10.32347/2411-4049.2020.4.32-40